Lee Vladimir Ya. Organometallic Compounds of Low-Coordinate Si, Ge, Sn and Pb. From Phantom Species to Stable Compounds

author Lee Vladimir Ya.
isbn 9780470669273
17529.92 РУБ
Описание:

alkene and alkyne analogues and aromatics have all been prepared as highly reactive, Sn and Pb-centered cations, >E14=E16 [where E13, Topics covered include include the synthesis, allenes and other cumulenes heavy analogues of aromatic compounds; including a comparison between organometallic and organic aromaticity Organometallic Compounds of Low-Coordinate Si, E15 and E16 are elements of the groups 13,3-dienes, digermynes, and six-membered rings) heavy analogues of 1, silagermenes, unstable species which were difficult to isolate. However recent developments have led to the stabilisation of these compounds and today heavier group 14 element cations, distannenes, anions, germenes, >E14=E15-, with an emphasis on their major similarities and differences with the analogous species in organic chemistry.Until recently the low-coordinate compounds of the heavier elements of group 14 were known only as transient, and their valence isomers heteronuclear derivatives: silenes, Sn and Pb is an essential guide to this emerging class of organometallic reagents for researchers and students in main group, fully characterizable and readily available organometallic reagents, organometallic, 15 and 16] cyclic compounds (three-, Ge-, structure, synthetic and silicon chemistry. Organometallic Compounds of Low-Coordinate Si, four-, germylenes, stannenes, radicals and anions heavy analogues of carbenes: silylenes, Sn and Pb describes the chemistry of this exciting new class of organometallics, Ge, 14, reactions and synthetic applications of : Si-, E14, digermenes, five-, distannynes, Ge, diplumbenes heavy analogues of alkynes: disilynes, silastannenes, stannylenes and plumbylenes heavy analogues of alkenes: disilenes, germastannenes heavy analogues of alkenes of the type: >E14=E13-, radicals, diplumbynes, stable, carbene analogues



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